The 42- year-old left the staff at Chelsea and joins the Dutch club to become a member of their first XI coaching team.
Myers, who made more than 100 first team appearances when he was still playing, worked during eight years as a Chelsea Academy coach.
Myers announced via Chelseas's website:
"I'm looking forward to joining the coaching staff of Vitesse.
I know Vitesse and their style of play and I hope to develop together with the staff".