The returning left-back marked his reappearance with a fantastic goal to pull his team back into the match that they had been trailing in.
Julen Lopetegui introduced Karim Benzema, Garteh Bale and Dani Ceballos in the second half in an effort to turn the game around.
It was Benzema who fed the Brazilian defender with a simple pass after collecting an over hit cross.
Marcelo did phenomenally well to take a touch and unleash a fantastic strike into the top corner with his weaker foot.