Gareth Southgate's side need two points from their final two games to secure qualification to next summer's World Cup, so a win against Slovenia on Thursday night would clinch it.
England sit top of Group F with 20 points, five ahead of second placed Slovakia, while Slovenia are in third place with 14 points.
The reverse fixture between these two sides in October 2016 ended in a narrow 0-0 draw.
Fabian Delph and Phil Jones have both withdrawn from the England squad through injury and Dele Alli will miss out due to a suspension, while Slovenia head into the tie with a full-strength squad.
Here are the potential lineups:
England: Hart; Walker, Stones, Cahill, Bertrand; Henderson, Dier; Oxlade-Chamberlain, Sterling, Rashford; Kane.
Slovenia: Oblak; Skubic, Mevlja, Cesar, Viler; Kurtic, Rotman, Verbic; Repas; Ilicic, Sparer.